What does she after school do? либо What does she do

 What does she do after school? Что она делает после школы?

 This sentence is correct.  

What does she after school do? This sentence is incorrect.

In English every word has its own place in the sentence. Here we have a special question.  Special question is formed with the help of an interrogative word.  

Interrogative word stands at the beginning of the sentence. Auxiliary is after the interrogative word. Subject is after the auxiliary. Verb stands after subject. Words that shows time and place are in the end of sentence.

Interrogative word + auxiliary + subject + verb + place + time.